3 per cent of electricity generation globally in the first half of 2025, while coal accounted for 33. This is roughly the equivalent of adding China, the European Union and Japan's power generation capacity combined to the global energy mix. Solar PV accounts for almost 80% of the global increase, followed by wind, hydropower, bioenergy and geothermal. Together, they have surpassed coal as an energy source for the first time.
Through breaking the anionic solvation barrier, synergistic interfacial modulation can be achieved by the formation of robust anion-derived inorganic-rich electrode-electrolyte interfaces on both the cathode and anode.
Therefore, suppressing the thermal runaway propagation (TRP) within battery systems is of great significance. TR can rapidly propagate within the battery system, primarily through thermal propagation and fire propagation.
If a barrier material integrated with gas regulation function can be developed and strategically placed between batteries, then in the event of battery TR, this material will not only prevent TRP but also release inert gas, effectively isolating combustible gases from ignition sources (such as high-temperature surfaces, electric arcs, etc.).
Li et al. developed a barrier material with both heat absorption and insulation functions by filling PCM into ceramic fibers. This material can reduce the peak temperature of battery TR and successfully inhibit the thermal propagation of 50 Ah LIBs.
Under high-temperature conditions, the mechanical properties of barrier materials are spontaneously enhanced. The thermal runaway propagation of high-capacity lithium iron phosphate batteries is suppressed. The danger associated with gas generation during thermal runaway in lithium iron phosphate batteries is reduced.
Traditional polypropylene, polyethylene, and polyimide separators are constrained by their inherent limitations, rendering them unsuitable for direct application in lithium–sulfur batteries. Therefore, there is an urgent need for the development of novel separators.
The blank battery module underwent TRP within 220 s after the first battery experienced TR, while the addition of CFP extended this time to 650 s. It is noteworthy that CFP exhibited poor thermal insulation performance in this study, with a maximum temperature difference of only 99℃ on both sides of the CFP, as shown in Fig. 6 (d).
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